(RP,R′P)-1,1′-双[双(4-甲氧基-3,5-二甲苯基)膦基]-2,2′-双[(S)-α-(二甲氨基)苯甲基]二茂铁 - Names and Identifiers
Name | (RP,R'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(S)-α-(dimethylamino)benzyl]ferrocene
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Synonyms | SL-M004-2 (RP,R'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(S)-α-(dimethylamino)benzyl]ferrocene (1R)-1-[2-bis(4-methoxy-3,5-dimethylphenyl)phosphanylcyclopenta-2,4-dien-1-yl]-N,N-dimethyl-1-phenylmethanamine (1S,1'S)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(S)-(dimethylamino)phenylmethyl]ferrocene (R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene Ferrocene,1,1'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(S)-(dimethylamino)phenylmethyl]-,(1S,1'S)- (9CI)
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CAS | 849925-12-8
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(RP,R′P)-1,1′-双[双(4-甲氧基-3,5-二甲苯基)膦基]-2,2′-双[(S)-α-(二甲氨基)苯甲基]二茂铁 - Physico-chemical Properties
Molecular Formula | 2C32H37NO2P.Fe
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Molar Mass | 1053.09 |
Storage Condition | Room Temprature |
(RP,R′P)-1,1′-双[双(4-甲氧基-3,5-二甲苯基)膦基]-2,2′-双[(S)-α-(二甲氨基)苯甲基]二茂铁 - Risk and Safety
WGK Germany | 3 |
HS Code | 29319090 |
(RP,R′P)-1,1′-双[双(4-甲氧基-3,5-二甲苯基)膦基]-2,2′-双[(S)-α-(二甲氨基)苯甲基]二茂铁 - Introduction
(RP,R'P)-1,1 '-bis [bis (4-methoxy-3, 5-xylyl) phosphino]-2,2'-bis [(S)-α-(dimethylamino) benzyl] ferrocene is a metal-organic complex. Its nature, use, preparation and safety information are given below.
Nature:
-Appearance: It is a solid substance, usually golden yellow crystals.
-Molecular formula: C52H58FeN2O2P4
-Molecular weight: 893.88g/mol
-Melting point: about 170-172°C
-It is stable at room temperature and can be dissolved in common solvents.
Use:
(RP,R'P)-1,1 '-bis [bis (4-methoxy-3, 5-xylyl) phosphino]-2,2'-bis [(S)-α-(dimethylamino) benzyl] ferrocene is a chiral ligand commonly used to catalyze asymmetric synthesis reactions. It can form chiral coordination compounds with transition metals for catalytic asymmetric hydrogenation, asymmetric hydrogenation, asymmetric oxidation, asymmetric carbon-carbon bond formation and other reactions.
Preparation Method:
The preparation of (RP,R'P)-1,1 '-bis [bis (4-methoxy-3, 5-xylyl) phosphino]-2,2'-bis [(S)-α-(dimethylamino) benzyl] ferrocene is complex and usually involves a series of steps in the synthesis and purification process.
Safety Information:
There is no clear report on the safety information of (RP,R'P)-1,1 '-bis [bis (4-methoxy-3, 5-xylyl) phosphino]-2,2'-bis [(S)-α-(dimethylamino) benzyl] ferrocene. However, as a general rule for handling organometallic compounds, safe operating procedures should be followed and appropriate protective measures should be taken, including wearing gloves, goggles and laboratory clothing to prevent contact with skin and inhalation. Inhalation of dust and dissolved matter should be avoided during handling. It is best to conduct a safety assessment before use and operate according to laboratory safety guidelines. Seek medical help in case of accidental exposure or ingestion.
Last Update:2024-04-10 22:29:15